Comments on “Experimental Multivalent Ionic Radii”

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Effective Ionic Radii in Oxides and Fluorides*

BHUIYA, A. K. & STANLEY, E. (1963). Acta Cryst. 16, 981. BUSING, W. R., MARTIN, K. O. & LEVY, H. A. (1962). ORFLS: A FORTRAN Crystallographic Least-Squares Program. Oak Ridge National Laboratory, Oak Ridge, Tennessee. CADY, H. H. (1967). Acta Cryst. 23, 601. DANIELSEN, J. (1963). ALGOL Program D45. Univ. of Aarhus, Denmark. FOLTING, K., LrPSCOMB, W. N. & JERSLEV, B. (1964). Acta Cryst. 17, 1263...

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Molar Volume, Ionic Radii in Stoichiometric and Nonstoichiometric Metal Oxides

Metal oxides are a group of compounds that are now intensively studied because of their wide use in modern ceramic materials, composites, nano-composites, etc., with new special properties. Many oxides are used as electronic materials for their electrical, magnetic and optical properties. The mechanisms of corrosion of metals and their alloys, as well as the mechanism of reduction in metallurgi...

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Corrigendum: Atomic and Ionic Radii of Elements 1-96.

Atomic and cationic radii have been calculated for the first 96 elements, together with selected anionic radii. The metric adopted is the average distance from the nucleus where the electron density falls to 0.001 electrons per bohr(3) , following earlier work by Boyd. Our radii are derived using relativistic all-electron density functional theory calculations, close to the basis set limit. The...

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Revised ionic radii of lanthanoid(III) ions in aqueous solution.

A new set of ionic radii in aqueous solution has been derived for lanthanoid(III) cations starting from a very accurate experimental determination of the ion-water distances obtained from extended X-ray absorption fine structure (EXAFS) data. At variance with previous results, a very regular trend has been obtained, as expected for this series of elements. A general procedure to compute ionic r...

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Controlling the formation of metallosupramolecular assemblies by metal ionic radii.

The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the size of the metal ion.

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ژورنال

عنوان ژورنال: Nature

سال: 1969

ISSN: 0028-0836,1476-4687

DOI: 10.1038/2241019a0